181149-13-3

Basic information

• Product Name: (E)-3-ferrocenyl(phenyl)boryl-1-phenyl-2-trimethylstannyl-2-propene
• CAS NO: 181149-13-3
• Molecular Weight: 552.922
• Mol File: 181149-13-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-3-ferrocenyl(phenyl)boryl-1-phenyl-2-trimethylstannyl-2-propene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-ferrocenyl(phenyl)boryl-1-phenyl-2-trimethylstannyl-2-propene(181149-13-3)
• EPA Substance Registry System: (E)-3-ferrocenyl(phenyl)boryl-1-phenyl-2-trimethylstannyl-2-propene(181149-13-3)

Safety Data

• Hazardous Substances Data: 181149-13-3(Hazardous Substances Data)

Upstream product

• 181149-08-6 diphenylborylferrocene 
• 1692-19-9 trimethyl(1-propynyl)stannane 

Relevant articles and documents

1,1-Organoboration of Trimethyl-1-propynyltin Using Diorganoboryl-Substituted Ferrocenes

The reactions of various diorganoborylferrocenes, Fc-BR2 [1, R = Me (a), Et (b), iPr (c), tBu (d), Ph (f), R2B = 9-borabicyclo[3.3.1]nonyl (e)] and 1,1′-bis(9-borabicyclo[3.3.1]nonyl)-ferrocene (2) with trimethyl-1-propynyltin (3) were studied, and the products of the 1,1-organoboration were characterized as the alkenyltin compounds 4-6 by 1H, 11B, 13C and 119Sn NMR. In the cases of 1a-1d and 1f, there is competition between the transfer of a ferrocenyl group and the other organyl groups R from boron to carbon, whereas in the case of the 9-borabicyclo[3.3.1]nonane derivatives 1e and 2, the enlargement of the bicyclic system takes place selectively (compounds 4e and 6). The molecular structure of the product 6, obtained from the reaction between the 1,1′-diborylated ferrocene 2 and two equivalents of 3, was determined by single crystal X-ray analysis (space group P21/c; monoclinic; Z = 4, a = 958.3(2), b = 1610.4(3), c = 2405.3(5) pm and β= 90.33(3)°).