181265-34-9Relevant articles and documents
Construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia
Semakin, Artem N.,Kokuev, Aleksandr O.,Nelyubina, Yulia V.,Sukhorukov, Alexey Yu.,Zhmurov, Petr A.,Ioffe, Sema L.,Tartakovsky, Vladimir A.
supporting information, p. 2471 - 2477 (2016/12/09)
Exhaustive Michael-type alkylations of amines and ammonia with azoalkenes (generated from α-halohydrazones) were demonstrated as an efficient approach to poly(hydrazonomethyl)amines - a novel class of polynitrogen ligands. An intramolecular cyclotrimerization of C=N bonds in tris(hydrazonomethyl)amine to the respective 1,4,6,10-tetraazaadamantane derivative was demonstrated.