181310-62-3Relevant articles and documents
Addition du Methylazide aux Olefines Portant une Double Substitution Activante Geminee. Etude de la Stabilite Thermique des Triazol-1,2,3-inees Obtenues
Hetet, G. Le,Danion-Bougot, R.,Carrie, R.
, p. 259 - 272 (2007/10/03)
Methylazide reacts with alkenes bearing two electron-withdrawing substituents on the same sp2 carbone and leads to corresponding 1,2,3-triazolines with these substituents in 4 position.Thermolysis of these 1,2,3-triazolines give cycloreversion (alkene + methylazide) and aziridines after extrusion of nitrigen.In the conditions of the thermolysis, aziridine carbone-carbone bond breaks, leading to azomethine ylids that are trapped with alkenes and give pyrrolidines.