181312-46-9Relevant academic research and scientific papers
Rearrangements of alkyne and 1,3-diyne in transition metal center forming small ring complexes
Yamazaki, Shinsaku
, p. 1 - 18 (2011/03/21)
CC bond coupling of alkynes(s) and alkynyl(s) mediated by transition metal complexes have recently lead to isolations of the small organometallic ring constituted of unsaturated carbon atoms of the dimer ligand. The ring structures of four-membered 1-meta
Stepwise insertion of alkylisocyanides into the metal-alkyne bond of half-sandwich type rhodium complexes: Synthesis and structural characterization of metallacyclobutenes and metallacyclopentenes
Werner, Helmut,Heinemann, Anja,Windmueller, Bettina,Steinert, Paul
, p. 903 - 910 (2007/10/03)
The cyclopentadieny! complexes [C5H5Rh(RC=CR′)(SbiPr3)] (5-8), which were prepared from frans-[RhCl(RC=CR′)(SbJPr3)2] (1-4) and NaC5H5 and which contain a labile Rh-SbiPr3/
