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Phosphoric acid, dimethyl trimethylsilyl ester is a chemical compound with the molecular formula C7H21O4PSi. It is a silylating agent used in the derivatization of alcohols, phenols, and carboxylic acids for gas chromatography-mass spectrometry (GC-MS) analysis. It is also employed in the synthesis of silyl enol ethers and protected carboxylic acids. This clear, colorless liquid has a strong odor and is highly flammable, making it a hazardous substance that requires proper safety precautions during handling and storage.

18135-13-2

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18135-13-2 Usage

Uses

Used in Analytical Chemistry:
Phosphoric acid, dimethyl trimethylsilyl ester is used as a derivatization agent for the analysis of alcohols, phenols, and carboxylic acids in gas chromatography-mass spectrometry (GC-MS). It helps in converting these compounds into more volatile and thermally stable derivatives, improving their detection and analysis.
Used in Organic Synthesis:
In the field of organic synthesis, Phosphoric acid, dimethyl trimethylsilyl ester is used as a reagent for the synthesis of silyl enol ethers and protected carboxylic acids. These compounds are important intermediates in various organic reactions and can be used to form a wide range of products.

Check Digit Verification of cas no

The CAS Registry Mumber 18135-13-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,8,1,3 and 5 respectively; the second part has 2 digits, 1 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 18135-13:
(7*1)+(6*8)+(5*1)+(4*3)+(3*5)+(2*1)+(1*3)=92
92 % 10 = 2
So 18135-13-2 is a valid CAS Registry Number.

18135-13-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name dimethyl trimethylsilyl phosphate

1.2 Other means of identification

Product number -
Other names Dimethyl-trimethylsilylphosphonat

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:18135-13-2 SDS

18135-13-2Relevant academic research and scientific papers

REACTIONS OF PHOSPHITES WITH TRICHLOROACETONITRILE

Kutyrev, A. A.,Moskva, V. V.,Alparova, M. V.

, p. 1332 - 1336 (2007/10/02)

Dialkyl hydrogen, sodium dialkyl, and dialkyl silyl phosphites react with trichloroacetonitrile by the Atherton-Todd scheme.Trialkyl phosphites add at the C(*)N bond of trichloroacetonitrile with the formation of trialkyl phosphorimidates.

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