18142-54-6Relevant academic research and scientific papers
Preparation of vinylsilane from monosilane and vinyl chloride
Itoh, Masayoshi,Iwata, Kenji,Kobayashi, Mineo
, p. 36 - 41 (1999)
Vinylsilane (CH2=CH-SiH3) was prepared by the dehydrochlorination reaction between SiH4 and vinyl chloride. The reactions were carried out in the gas phase at 450-500°C using a tube reactor, and the maximum yield of vinylsilane was 21% when the conversion of SiH4 was 32%. A small amount of CCl4 and CH3NO2 accelerated the reaction. A reaction mechanism involving :SiH2, which was generated by the thermal decomposition of SiH4, was proposed.
