18142-56-8Relevant academic research and scientific papers
Preparation of vinylsilane from monosilane and vinyl chloride
Itoh, Masayoshi,Iwata, Kenji,Kobayashi, Mineo
, p. 36 - 41 (2007/10/03)
Vinylsilane (CH2=CH-SiH3) was prepared by the dehydrochlorination reaction between SiH4 and vinyl chloride. The reactions were carried out in the gas phase at 450-500°C using a tube reactor, and the maximum yield of vinylsilane was 21% when the conversion of SiH4 was 32%. A small amount of CCl4 and CH3NO2 accelerated the reaction. A reaction mechanism involving :SiH2, which was generated by the thermal decomposition of SiH4, was proposed.
MONOFLUORINATION OF SOME DIHYDROSILANES
Hong, Cun-Mao,Witt, Sheila D.,Tang, Yi-Noo
, p. 359 - 370 (2007/10/02)
The heterogeneous fluorination of diethylsilane, ethylvinylsilane and divinylsilane with SbF5 was studied by measuring the yields of the fluorinated products as a function of reaction time.As the reactions proceed, the monoflorinated species (two of them are new compounds) exhibit maxima in their percentage yields with respect to time. the proton NMR and IR spectra of the three silanes and their six fluorinated products are reported.
