18145-64-7Relevant articles and documents
Synthesis and chemical properties of 1,3-dichloro-1,3-dihydridodisilazanes
Bacque, Eric,Pillot, Jean-Paul,Birot, M.,Dunogues, J.,Bourgeois, G.,Petraud, M.
, p. 167 - 172 (2007/10/02)
A trans-silylation route to 1,3-dichloro-1,3-dihydridodisilazanes, a novel class of polyfunctional disilazane, is described.Thus, heating hexamethyl- or heptamethyl-disilazane under reflux in the presence of an excess of dichlorohydrogenosilane R1SiHCl2, led to compounds of formula (R1ClHSi)2NR2 (R1=Me, Et, Vi or Ph and R2=H; R1=Me and R2=Me) in high yield.The exchange of chlorinated organosilicon moieties was strongly facilited by a catalytic amount of (n-Bu4N)F.Interpretation of the results and a few chemical properties of these novel disilazanes arereported.Key words: Silicon; Silazanes; Synthesis; Dichlorodisilazanes; Dihydridodisilazanes