18146-00-4

Basic information

• Product Name: ALLYLOXYTRIMETHYLSILANE
• Synonyms: (2-Propenyloxy)trimethylsilane;3-(Trimethylsilyloxy)-1-propene;Allyloxytrimethylsilane,98%;Trimethylsilylallyl ether;3-(Trimethylsiloxy)propene ;Allyloxytrimethylsilane(O-Trimethylsilylallylalcohol);O-TRIMETHYLSILYLALLYL ALCOHOL;1-Trimethylsiloxy-2-propene
• CAS NO: 18146-00-4
• Molecular Formula: C₆H₁₄OSi
• Molecular Weight: 130.26
• EINECS: 242-031-4
• Product Categories: Acyclic;Alkenes;Building Blocks;Chemical Synthesis;Organic Building Blocks;monomer;Monoalkoxysilanes;Si (Classes of Silicon Compounds);Silicon Compounds (for Synthesis);Si-O Compounds;Synthetic Organic Chemistry;Vinylsilanes, Allylsilanes
• Mol File: 18146-00-4.mol
• Article Data: 32

Chemical Properties

• Melting Point: <0°C
• Boiling Point: 100-102 °C(lit.)
• Flash Point: 31 °F
• Appearance: clear colorless liquid
• Density: 0.773 g/mL at 25 °C(lit.)
• Vapor Pressure: 38mmHg at 25°C
• Refractive Index: n20/D 1.397(lit.)
• Storage Temp.: 2-8°C
• Sensitive: Moisture Sensitive
• BRN: 1739517
• CAS DataBase Reference: ALLYLOXYTRIMETHYLSILANE(CAS DataBase Reference)
• NIST Chemistry Reference: ALLYLOXYTRIMETHYLSILANE(18146-00-4)
• EPA Substance Registry System: ALLYLOXYTRIMETHYLSILANE(18146-00-4)

Safety Data

• Hazard Codes: F,Xi
• Statements: 11-36/37/38
• Safety Statements: 16-26-36
• RIDADR: UN 1993 3/PG 2
• WGK Germany: 3
• F: 10-21
• TSCA: Yes
• HazardClass: 3.1
• PackingGroup: II
• Hazardous Substances Data: 18146-00-4(Hazardous Substances Data)

Usage

Chemical Properties

clear colorless liquid

Uses

Allyloxytrimethylsilane is used in the synthesis of metalated dienes via an isomerization-elimination sequence. Allyloxytrimethylsilane [3-(Trimethylsiloxy)propene] was used in the synthesis of trimethylsilyl protected (3-hydroxypropyl)-trimethoxysilane. Used in preparation of electrical materials, OLED, and in Pharma industry.

InChI:InChI=1/C6H14OSi/c1-5-6-7-8(2,3)4/h5H,1,6H2,2-4H3

Upstream product

• 71821-60-8 1-(allyloxy)pentamethyldisilane 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 
• 43112-38-5 3-(trimethylsilyl)-2-oxazolidinone 
• 107-18-6 allyl alcohol 
• 104915-79-9 trimethyl-(1H,1H,9H-hexadecafluorononyloxy)silane 
• 479486-96-9 N,N-dimethyl (trimethylsilyl)methanamide 
• 101347-32-4 1,1-bis(allyloxy)tetramethyldisilane 
• 56002-63-2 trimethyl-(1H,1H,5H-octafluoropentyloxy)silane 
• 56002-69-8 trimethyl-(1H,1H,3H-tetrafluoropropoxy)silane 
• 56002-71-2 trimethyl-(1H,1H,7H-dodecafluoroheptyloxy)silane 
• 18297-63-7 N,N'-bis(trimethylsilyl)urea 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 
• 1112-39-6 dimethyldimethoxysilan 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 

Downstream Products

• 18036-77-6 1-phenylsilanyl-3-trimethylsilanyloxy-propane 
• 18171-24-9 γ-Hydroxypropyl-chlormethyl-dimethyl-silan 
• 17891-49-5 (γ-Trimethylsiloxypropyl)-chlormethyl-dimethyl-silan 
• 59906-42-2 1-(1-Trimethylsilanyloxy-allyl)-cyclohex-2-enol 
• 18052-66-9 3-Trimethylsilyloxy-3-benzoyloxy-propen-⁽¹⁾ 
• 762-72-1 allyl-trimethyl-silane 
• 14371-10-9 (E)-3-phenylpropenal 
• 1825-61-2 Trimethylmethoxysilane 
• 101347-37-9 Allyloxy-methoxy-dimethyl-silane 
• 27122-63-0 allyl (+/-)-1-phenylethyl ether 
• 57340-62-2 ((E)-1-Allyl-2-methyl-penta-1,4-dienyl)-benzene 
• 80586-92-1 Allyl cinnamyl ether 
• 56318-28-6 (bis(allyloxy)methyl)benzene 
• 223562-74-1 (3-allyloxy-hex-5-enyl)-benzene 

Relevant articles and documents

Immobilization of biomolecules via ruthenium-catalyzed functionalization of the surface of silica with a vinylsilane

A new ruthenium complex catalyzed procedure for the efficient O-silylation of an SiO-H group on the silica surface of glass beads with controlled pores (CPG) using 1-trimethylsiloxy-3-dimethylvinylsilylpropane leading to Si-O-Si bond formation with the evolution of ethylene is described. The formed linker contains alkyl hydroxyl groups which can be reacted with a nucleoside phosphoramidite unit. The CPG support containing alkyl hydroxyl groups is successfully applied in automatic chemical synthesis of DNA fragments.

Synthesis of bifunctional disiloxanes: Via subsequent hydrosilylation of alkenes and alkynes

The first protocol for the synthesis of unsymmetrical bifunctional 1,1,3,3-tetramethyldisiloxane derivatives via subsequent hydrosilylation of alkenes and alkynes is presented. The methodology described has vast functional group tolerance and is extremely efficient towards the formation of novel disiloxane-based building blocks.

Room-Temperature Gold-Catalysed Arylation of Heteroarenes: Complementarity to Palladium Catalysis

Tailoring of the pre-catalyst, the oxidant and the arylsilane enables the first room-temperature, gold-catalysed, innate C?H arylation of heteroarenes. Regioselectivity is consistently high and, in some cases, distinct from that reported with palladium ca

Microwave-assisted synthesis of 1,3-bis(3-hydroxypropyl)-1,1,3,3-tetramethyldisiloxane

1,3-Bis(3-hydroxypropyl)-1,1,3,3-tetramethyldisiloxane was synthesized under microwave irradiation. The structure of the compound was analyzed by infrared spectroscopy, nuclear magnetic resonance hydrogen spectroscopy and gas chromatography. The optimal reaction condition was obtained by the single factor method. Under the optimal condition, the overall yield could reach 83.9 % and the purity of 1,3-bis(3-hydroxypropyl)-1,1,3,3-tetramethyldisiloxane was 99.1 %. It is found that under microwave radiation the reactions are very rapid with good yield, better quality and less time is required for the completion of the reaction.