18158-42-4

Basic information

• Product Name: 4'-chloro-N,N-dimethyl-[1,1'-biphenyl]-4-amine
• Synonyms: 4'-chloro-N,N-dimethyl-[1,1'-biphenyl]-4-amine
• CAS NO: 18158-42-4
• Molecular Weight: 231.725
• Mol File: 18158-42-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4'-chloro-N,N-dimethyl-[1,1'-biphenyl]-4-amine(CAS DataBase Reference)
• NIST Chemistry Reference: 4'-chloro-N,N-dimethyl-[1,1'-biphenyl]-4-amine(18158-42-4)
• EPA Substance Registry System: 4'-chloro-N,N-dimethyl-[1,1'-biphenyl]-4-amine(18158-42-4)

Safety Data

• Hazardous Substances Data: 18158-42-4(Hazardous Substances Data)

Upstream product

• 112529-05-2 1,1,2,2-Tetrafluoro-2-(1,1,2,2-tetrafluoro-ethoxy)-ethanesulfonic acid 4-chloro-phenyl ester 
• 121-69-7 N,N-dimethyl-aniline 
• 29540-84-9 4-chlorophenyl trifluoromethanesulfonate 

Downstream Products

• 942589-53-9 2-(4'-chloro-[1,1'-biphenyl]-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Relevant articles and documents

Photo-induced electron-transfer reaction of aryl perfluoroalkanesulfonates with anilines

Irradiation of mixtures of aryl perfluoroalkanesulfonates (RfSO3C6H4X-p, X = H, Cl and Me) (1) and aniline (2a), N,N-dimethylaniline (2b) or N,N-diethylaniline (2c) results in the formation of 2-coupling products 3 and 4-coupling products 4.However, in the reactions of 2b and 2c, in addition to 3 and 4, arenes 5 and N-methylaniline (6a) or N-ethylaniline (6b) are also detected.The presence of p-dinitrobenzene, But2NO and hydroquinone suppresses the reaction significantly.A photo-induced electron-transfer mechanism is proposed.