18159-25-6

Basic information

• Product Name: 2-(2,4-dinitrobenzenesulfenyl)pyrrole
• Synonyms: 2-(2,4-dinitrobenzenesulfenyl)pyrrole
• CAS NO: 18159-25-6
• Molecular Weight: 265.249
• Mol File: 18159-25-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(2,4-dinitrobenzenesulfenyl)pyrrole(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2,4-dinitrobenzenesulfenyl)pyrrole(18159-25-6)
• EPA Substance Registry System: 2-(2,4-dinitrobenzenesulfenyl)pyrrole(18159-25-6)

Safety Data

• Hazardous Substances Data: 18159-25-6(Hazardous Substances Data)

Upstream product

• 109-97-7 pyrrole 
• 528-76-7 2,4-dinitrobenzenesulfenyl chloride 

Downstream Products

• 2486-09-1 2,4-dinitro-1-phenylsulfanyl-benzene 
• 852360-81-7 2-(2,4-dinitrobenzenesulfonyl)pyrrole 
• 852360-80-6 2-(2,4-dinitrobenzenesulfinyl)pyrrole 
• 18159-26-7 5-(2,4-dinitrobenzenesulfenyl)pyrrole-2-carboxaldehyde 

Relevant articles and documents

Sulfur-based protecting groups for pyrroles and the facile deprotection of 2-(2,4-dinitrobenzene)sulfinyl and sulfonyl pyrroles

(Chemical Equation Presented) The effectiveness of simple sulfinyl and sulfonyl groups as electron-withdrawing protecting groups for pyrroles has been analyzed using 13C NMR spectroscopy and confirmed by consideration of X-ray crystal structures. Additionally, the 2,4-dinitrobenzenesulfinyl and sulfonyl groups are shown to be effective electron-withdrawing protecting groups for pyrroles, and they can be removed by treatment with benzene thiol or thiolate under mild and specific conditions.