181637-39-8

Basic information

• Product Name: ((1R,3S)-1-Furan-2-yl-3,4-dihydroxy-butyl)-carbamic acid benzyl ester
• Synonyms: ((1R,3S)-1-Furan-2-yl-3,4-dihydroxy-butyl)-carbamic acid benzyl ester
• CAS NO: 181637-39-8
• Molecular Weight: 305.331
• Mol File: 181637-39-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ((1R,3S)-1-Furan-2-yl-3,4-dihydroxy-butyl)-carbamic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: ((1R,3S)-1-Furan-2-yl-3,4-dihydroxy-butyl)-carbamic acid benzyl ester(181637-39-8)
• EPA Substance Registry System: ((1R,3S)-1-Furan-2-yl-3,4-dihydroxy-butyl)-carbamic acid benzyl ester(181637-39-8)

Safety Data

• Hazardous Substances Data: 181637-39-8(Hazardous Substances Data)

Upstream product

• 181637-34-3 N-[(1R,3S)-4-(tert-Butyl-diphenyl-silanyloxy)-1-furan-2-yl-3-hydroxy-butyl]-4-methyl-benzenesulfonamide 
• 181637-31-0 N-((1R,3S)-1-Furan-2-yl-3,4-dihydroxy-butyl)-4-methyl-benzenesulfonamide 
• 501-53-1 benzyl chloroformate 
• 181637-37-6 [(1R,3S)-4-(tert-Butyl-diphenyl-silanyloxy)-1-furan-2-yl-3-hydroxy-butyl]-carbamic acid benzyl ester 

Downstream Products

• 132970-47-9 ((3R,5S)-5-Hydroxymethyl-2-oxo-tetrahydro-furan-3-yl)-carbamic acid benzyl ester 

Relevant articles and documents

A facile transformation of the δ-hydroxy-α-amino lactones from α- furfuryl amide

(S)- and (R)- α- furfuryl amides, obtained from the kinetic resolution of (R, S)- α- furfuryl amide using the modified Sharpless asymmetric epoxidation, have been transformed into four 8-hydroxy α- amino lactones (1S, 3S)-1, (1R, 3R)-1, (1S, 3R)-1, (1R, 3S)-1, using sharpless asymmetric dihydroxylation as the key step. The much more efficient method of the addition of chiral aldimine 10 with allylic Grignard reagent for preparation of (S, S)-1 was also achieved.