181645-35-2

Upstream product

• 163394-40-9 (C₂₂H₂₂N₄)ZrCl₂ 
• 181645-34-1 [Zr(NC₅H₅)(NC₆H₃(C₃H₇)2)(C₂₂H₂₂N₄)] 
• 24544-04-5 2,6-diisopropylbenzenamine 
• 186840-10-8 (tetramethyldibenzotetraaza[14]annulene^(2-))Zr(CH₂SiMe₃)2 
• 142839-70-1 [Zr(N-2,6-C₆H₃Pr(i)2)(NH-2,6-C₆H₃Pr(i)2)2(pyridine)2] 

Downstream Products

• 181645-39-6 Zr(N(C₆H₃(CH(CH₃)2)2)CON(C(CH₃)3))(C₂₂H₂₂N₄)*C₇H₈ 

Relevant academic research and scientific papers

Mononuclear Amido and Binuclear Imido Zirconium Complexes Supported by Dibenzotetraaza[14]annulene Ligands. X-ray Structure of [(Me4taa)Zr(μ-NR) 2Zr(NHR)2] (R = But or 2,6-C6H3Me2)

Reaction of 2 equiv of Li[NH-2,6-C6H3R2] with [(Me4taa)Zrcl2] (Me4taaH2 = tetramethyldibenzotetraaza[14]-annulene) gives the bis(amido) derivatives [(Me4taa)Zr(NH-2,6-C6H3R2) 2] [R = Pri (1) and Me (2)]. Addition of Me4taaH2 to [Zr(N-2,6-C6H3Pr2i)(NH-2,6-C 6H3Pr2i)2(py) 2] also affords 1. The reaction of 2 equiv of aryl or alkyl amines H2NR with the bis(alkyl) complex [(Me4taa)Zr(CH2SiMe3)2] is the most versatile method for preparing [(Me4taa)Zr(NHR)2] (R = 2,6-C6H3Pr2i, 2,6-C6H3Me2, Ph, or But). Reaction of 1 equiv of Me4taaH2 with the binuclear complexes [(ButNH)2Zr(μ-NBut)2Zr(NHBu t)2] or [(py)(HN-2,6-C6H3Me2) 2Zr(μ-N-2,6-C6H3Me2) 2Zr-(NH-2,6-C6H3Me2) 2(py)] gives the asymmetrically substituted derivatives [(Me4taa)Zr(μ-NR)2Zr(NHR)2] [R = But (6) or 2,6-C6H3Me2 (8)], which have been crystallographically characterized.

Cycloaddition reactions of tetraaza macrocycle supported group 4 imido complexes and reversible addition of aryl isocyanate to a coordinated ureate ligand

The first tetraaza macrocycle supported zirconium imido complex [Zr(tmtaa)(NC6H3Pri2-2,6)(py)] and the new titanium imido base-free analogues [Ti(tmtaa)(NAr)] (Ar = Ph or C6H4Me-4) react wi