18166-58-0Relevant academic research and scientific papers
REACTIONS OF ARYLDIAZONIUM TETRAFLUOROBORATES WITH ACRYLAMIDE IN THE PRESENCE OF THIOCYANATES, BROMIDES, AND CHLORIDES OF ALKALI METALS AND AMMONIUM
Grishchuk, B. D.,Gorbovoi, P. M.,Kudrik, E. Ya.,Ganushchak, N. I.
, p. 1620 - 1623 (2007/10/02)
The reaction of aryldiazonium tetrafluoroborates with acrylamide in a water-acetone mixture (1:2) in the presence of copper or iron salts and additives of thiocyanates (bromides, chlorides) of alkali metals and ammonium yields α-thiocyanato(bromo, chloro)-β-arylpropionamides. These compounds under the action of triethylamine easily eliminate hydrogen thiocyanate (bromide, chloride) with formation of β-arylacrylamides.
