181713-43-9Relevant academic research and scientific papers
1,4-asymmetric induction in the chromium(II)- and indium-mediated coupling of allyl bromides to aldehydes
Maguire, Robert J.,Mulzer, Johann,Bats, Jan W.
, p. 6936 - 6940 (2007/10/03)
A series of allyl bromides bearing an ethereal stereogenic substituent at C-2 were synthesized from methyl acrylate. These were coupled with a range of aldehydes under chromium(II) chloride-mediated conditions to afford syn-4-alkoxyalkan-1-ols in good yie
1,4-Asymmetric induction in the Nozaki-Hiyama reaction
Maguire, Robert J.,Mulzer, Johann,Bats, Jan W.
, p. 5487 - 5490 (2007/10/03)
A series of allyl bromides 3a-c bearing a stereogenic carbon substituent at C-2 are synthesized in four steps from methyl acrylate. These are found to react with aldehydes, mediated by chromium(II) chloride, to furnish syn-4-alkoxyalkan-1-ols 4 in good to
