181787-60-0

Basic information

• Product Name: N,N'-(1R,2R)-(-)-1,2-cyclohexylenebis(2-hydroxy-3-methoxy-benzyldeneimine)
• Synonyms: N,N'-(1R,2R)-(-)-1,2-cyclohexylenebis(2-hydroxy-3-methoxy-benzyldeneimine)
• CAS NO: 181787-60-0
• Molecular Weight: 382.459
• Mol File: 181787-60-0.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: N,N'-(1R,2R)-(-)-1,2-cyclohexylenebis(2-hydroxy-3-methoxy-benzyldeneimine)(CAS DataBase Reference)
• NIST Chemistry Reference: N,N'-(1R,2R)-(-)-1,2-cyclohexylenebis(2-hydroxy-3-methoxy-benzyldeneimine)(181787-60-0)
• EPA Substance Registry System: N,N'-(1R,2R)-(-)-1,2-cyclohexylenebis(2-hydroxy-3-methoxy-benzyldeneimine)(181787-60-0)

Safety Data

• Hazardous Substances Data: 181787-60-0(Hazardous Substances Data)

Upstream product

• 148-53-8 3-methoxy-2-hydroxybenzaldehyde 
• 32044-22-7 (1R,2R)-1,2-diaminocyclohexane tartrate 
• 32044-22-7 (1S,2S)-cyclohexane-1,2-diammonium 2,3-dihydroxysuccinate 
• 20439-47-8 (1R,2R)-1,2-diaminocyclohexane 

Relevant articles and documents

Asymmetric Oxidation of Sulfides to Sulfoxides by Organic Hydroperoxides with Optically Active Schiff Base-Oxovanadium(IV) Catalysts

The asymmetric oxidation of sulfides into the corresponding sulfoxides was achieved with organic hydroperoxides in the presence of a catalytic amount of optically active Schiff base-oxovanadium(IV) complexes; in most cases the optical yields (e.e.) ranged

Synthesis, Characterization, and in Vitro Cytotoxicity of Platinum(II) Complexes Bearing Chiral Tetradentate Salicylaldimine Ligands

A series of platinum(II) complexes with chiral Schiff base ligands derived from various salicylaldehydes with (R,R′)- and (S,S′)-cyclohexanediamine were synthesized and characterized by ESI-MS, IR, and NMR. Obtained spectra with typical signals were in agreement with suggested molecular formulae of the complexes. Their photophysical properties were studied by UV-visible and emission spectroscopies. The UV-Vis showed the typical band with low energy at visible range 400-500 nm for MLCT, and this band can emit the luminescent band with emission maximum wavelengths at 529-595 nm. The in vitro cytotoxicity of obtained platinum(II) complexes was screened for KB and MCF-7 human cancer cell lines. The results showed that (S)-enantiomers were more active than (R)-enantiomers and the different positions of methoxy group in salicyl ring gave different cytotoxicities.

A family of nickel-lanthanide heterometallic dinuclear complexes derived from a chiral Schiff-base ligand exhibiting single-molecule magnet behaviors

Abstract A new family of nickel-lanthanide heterometallic dinuclear complexes derived from a chiral Schiff-base ligand, (R,R)-N,N'-bis(3-methoxysalicylidene)cyclohexane-1,2-diamine (H2L), namely [Ni(L)Ln(NO3)3(H2/sub