181948-62-9Relevant academic research and scientific papers
Neutral and cationic nickel (II) complexes of phosphino-amines: [NiCl2(PMe2Ph)(PNMe2)] and [NiCl(PMe2Ph) (PNMe2)]PF6 (PNMe2 = N,N′-dimethyl-2-(diphenylphosphino) aniline)
Crociani, Laura,Refosco, Fiorenzo,Tisato, Francesco,Gatto, Stefano,Corain, Benedetto
, p. 131 - 133 (1996)
A neutral bidentate P,N-ligand combining a hard dimethylamino nitrogen and a soft phosphine phosphorus donor affords the neutral trigonal bipyramidal as well as the cationic square-planar nickel(II) complexes CU-[NiCl2(PMe2Ph) (PNMe2) ] and [NiCl(PMe2Ph) (PNMe2) ]PF6, respectively. The latter species exhibits an appreciable catalytic activity in propylene oligomerization in the presence of Et2AlCl as co-catalyst.
Phosphanyl-amino complexes of nickel(II): Synthesis and structure
Crociani, Laura,Tisato, Francesco,Refosco, Fiorenzo,Bandoli, Giuliano,Corain, Benedetto
, p. 1689 - 1697 (2008/10/08)
New neutral pentacoordinate nickel(II) complexes of the type [NiCl2(PR3)(P∩N)] [PR3 = PMe3, PMe2Ph, PMePh2; P∩N = 2-(diphenylphosphanyl)aniline (P∩NH2
