18197-55-2Relevant academic research and scientific papers
CYCLIC CARBALKOXY AMINIMIDES. SYNTHESIS AND THERMAL DECOMPOSITION TO GIVE N,N-DIMETHYLAMINO ISOCYANATE
Senet, Jean-Pierre,Vergne, Guyselaine,Wooden, Gary P.
, p. 6319 - 6322 (2007/10/02)
Five membered ring carbalkoxy aminimides are prepared from 1,1-dimethylhydrazine and α-chloroalkyl chloroformates in three steps.Upon heating, these aminimides give high yields of N,N-dimethylamino isocyanate.This intermediate dimerizes or can be trapped in the presence of a nucleophile.
