182154-52-5Relevant academic research and scientific papers
Sodium dithionite initiated addition of CF2Br2, CF3I and (CF3)2CFI to allylaromatics. Synthesis and the reactivity of 4-aryl-1,1-difluorodienes and 4-aryl-1,1-bis(trifluoromethyl)dienes
Ignatowska, Jolanta,Dmowski, Wojciech
, p. 997 - 1006 (2007)
Sodium dithionite initiated addition of CF2Br2, CF3I and (CF3)2CFI to the terminal double bond of allylbenzenes and of (CF3)2CFI to allylpyridines in a MeCN/H2O system
Reactions of 1,3-dibromo-1,1-difluoro compounds with 1,8-diazabicyclo[5.4.0]undec-7-ene
Elsheimer, Seth,Foti, Christopher J.,Bartberger, Michael D.
, p. 6252 - 6255 (2007/10/03)
Difluorodienes result from the double dehydrobromination of 4-aryl-1,3-dibromo-1,1-difluorobutanes with DBU. Attempted syntheses of analogous 4-alkyl or 4-alkoxy dienes yield monoelimination products under mild conditions and unexpected trifluoro compounds under more vigorous conditions. 4-Aryl-1,1-difluoro-1,3-butadienes react rapidly with 4-phenyl-1,2,4-triazoline-3,5-dione in Diels-Alder reactions, but these dienes are unreactive toward several other electron-deficient and electron-rich dienophiles.
