182186-53-4Relevant academic research and scientific papers
Preparation and reactions of half-sandwich rhenium nitrosyl complexes containing a tethered amino ligand
Wang, Tein-Fu,Lai, Ching-Yih,Wen, Yuh-Sheng
, p. 187 - 195 (1996)
The aminorhenium nitrosyl complex [η5:η1-C5H4CH2CH2N(CH3)2Re(NO)(CO)] + BF-4 (5a), in which the ligating amino group was connected to the cyclopentadienyl ring, was prepared by reacting the η5-C5H4CH2CH2N(CH3)2Re(NO)(CO)Br (4) with AgBF4. Reaction of 5a with alkylmetal reagents provided the acyl complex η5:η1-C5H4CH2CH2N(CH3)2Re(NO)COR (8) (R = n-butyl, methyl, ethyt, isopropyl, benzyl). Solid state structures of 5b (X-= BPh-4) and the acetyl complex 8b were characterized by single-crystal X-ray analyses.
