182247-45-6Relevant articles and documents
Highly enantioselective hydrogenation of itaconic acid derivatives with a chiral bisphospholane-Rh(I) catalyst
Almena, Juan,Monsees, Axel,Kadyrov, Renat,Riermeier, Thomas H.,Gotov, Battsengel,Holz, Jens,Boerner, Armin
, p. 1263 - 1266 (2007/10/03)
The new - commercially in multi-kg quantities available - chiral bisphospholane ligand, catA-Sium M, has been successfully used in the Rh(I)-catalysed enantioselective hydrogenation of itaconic acid derivatives. Chiral β-substituted succinic acid derivati
Synthetic study of AAL-toxins: Efficient construction of two vicinal diol moieties by asymmetric dihydroxylation
Oikawa, Hideaki,Kagawa, Takashi,Kobayashi, Tomonori,Ichihara, Akitami
, p. 6169 - 6172 (2007/10/03)
Asymmetric dihydroxylation has been applied to syntheses of two vicinal anti-diol moieties in key intermediates of AAL-toxins. The strategy allowed efficient construction of left- and right segments of AAL-toxin main chain.