182489-43-6

Basic information

• Product Name: Diethyl-carbamic acid 1-(2-methoxymethoxy-phenyl)-vinyl ester
• Synonyms: Diethyl-carbamic acid 1-(2-methoxymethoxy-phenyl)-vinyl ester
• CAS NO: 182489-43-6
• Molecular Weight: 279.336
• Mol File: 182489-43-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Diethyl-carbamic acid 1-(2-methoxymethoxy-phenyl)-vinyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Diethyl-carbamic acid 1-(2-methoxymethoxy-phenyl)-vinyl ester(182489-43-6)
• EPA Substance Registry System: Diethyl-carbamic acid 1-(2-methoxymethoxy-phenyl)-vinyl ester(182489-43-6)

Safety Data

• Hazardous Substances Data: 182489-43-6(Hazardous Substances Data)

Upstream product

• 57933-92-3 <(diethylcarbamoyl)oxy>ethylene 
• 80778-47-8 1-iodo-2-methoxymethoxybenzene 
• 68314-54-5 1-bromo-2-(methoxymethoxy)benzene 

Downstream Products

• 118-93-4 o-hydroxyacetophenone 

Relevant articles and documents

α-Zinc O-vinyl carbamates as anionic Friedel-Crafts equivalents. Cross coupling reactions with aryl and heteroaryl halides and triflates

A mild, efficient, and general Negishi cross coupling protocol, 4 + 5 → 6 is reported; the hydrolysis of products 6 to acetophenones demonstrates the anionic Friedel-Crafts equivalency of the overall synthetic operation.