182498-53-9

Upstream product

• 182498-49-3 (4R,5R)-5-[2-(5,8-Dimethoxy-naphthalen-2-yl)-ethyl]-4,5-dimethyl-cyclohex-2-enone 
• 182498-41-5 (4S,5S)-3-[2-(5,8-Dimethoxy-naphthalen-2-yl)-ethyl]-4-methyl-5-trimethylsilanyl-cyclohex-2-enone 
• 182498-43-7 (3R,4S,5S)-3-[2-(5,8-Dimethoxy-naphthalen-2-yl)-ethyl]-3,4-dimethyl-5-trimethylsilanyl-cyclohexanone 

Downstream Products

• 129196-56-1 cordiaquinone B 
• 182700-28-3 (2R,3S,4R)-3-[2-(5,8-Dimethoxy-naphthalen-2-yl)-ethyl]-2,3,4-trimethyl-cyclohexanone 

Relevant academic research and scientific papers

Total synthesis of (-)-cordiaquinone B

Enantioselective synthesis of the unnatural antipode of cordiaquinone B possessing a 3-substituted 2,3,4-trimethylcyclohexanone framework was accomplished starting with (4S, 5S)-4-methyl-5-trimethylsilyl-2-cyclohexen-1-one. By this synthesis, the absolute structure of (+)-cordiaquinone B has been established.