18254-57-4Relevant articles and documents
Lignin monomer conversion into biolubricant base oils
Ebikade, Elvis Osamudiamhen,Liu, Sibao,Sadula, Sunitha,Vlachos, Dionisios G.
supporting information, p. 10090 - 10100 (2021/12/27)
Despite progress in the depolymerization of lignin, only a few studies convert the obtained monomers to value-added products. Here we introduce a strategy to synthesize branched benzene lubricant (BBL) and branched cyclic lubricant (BCL) base oils from lignin-derived monomers and aldehyde. We perform carbon-carbon coupling via Br?nsted acid-catalyzed hydroxyalkylation/alkylation (HAA) then hydrodeoxygenation (HDO). Optimum HAA reaction conditions achieve up to 90% guaiacol conversion and an HAA product containing 76% BBL and 24% enal condensation product over a P-SiO2 catalyst. Subsequent HDO of HAA products over an Ir-ReOx/SiO2 catalyst produces a lubricant-ranged mixture of BCL (C24) up to yield (82%) and small fractions of dodecyl cyclohexane and C10 and C15 carbons alkanes. The kinematic viscosity, viscosity index, and Noack volatility of these base oils are comparable to commercial petroleum-derived poly α-olefin Group IV and refrigerant base oils. This approach provides a sustainable pathway for replacing petroleum-derived base oils.
