18278-24-5

Basic information

• Product Name: 1-NAPHTHALENECARBOXALDEHYDE, 1,2,3,4-TETRAHYDRO-
• Synonyms: 1,2,3,4-Tetrahydro-naphthalene-1-carbaldehyde;1-NAPHTHALENECARBOXALDEHYDE, 1,2,3,4-TETRAHYDRO-
• CAS NO: 18278-24-5
• Molecular Formula: C11H12O
• Molecular Weight: 160.21
• Mol File: 18278-24-5.mol
• Article Data: 18

Chemical Properties

• Appearance: /
• Storage Temp.: Inert atmosphere,Store in freezer, under -20°C
• CAS DataBase Reference: 1-NAPHTHALENECARBOXALDEHYDE, 1,2,3,4-TETRAHYDRO-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-NAPHTHALENECARBOXALDEHYDE, 1,2,3,4-TETRAHYDRO-(18278-24-5)
• EPA Substance Registry System: 1-NAPHTHALENECARBOXALDEHYDE, 1,2,3,4-TETRAHYDRO-(18278-24-5)

Safety Data

• Hazardous Substances Data: 18278-24-5(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 25, p. 3007, 1984 DOI: 10.1016/S0040-4039(01)81350-2

Upstream product

• 529-34-0 3,4-dihydronaphthalene-1(2H)-one 
• 88533-92-0 (+/-)-trans-6-Bromo-6,7,8,9-tetrahydro-5-hydroxy-5H-benzocycloheptene 
• 96396-95-1 1,1'-Oxido-tetralinessigsaeure-⁽¹⁾ 
• 201801-48-1 1,2,3,4-tetrahydro-1-(methoxymethylene)naphthalene 
• 93340-32-0 3,4-dihydro-1-naphthalenecarboxaldehyde 
• 447-53-0 1,2-Dihydronaphthalene 
• 201230-82-2 carbon monoxide 
• 155566-54-4 1,2,3,4-tetrahydro-1-naphthalenecarbaldehyde 
• 85977-52-2 (S)-1,2,3,4-tetrahydronaphthalene-1-carboxylic acid 
• 17502-86-2 Methyl 1,2,3,4-tetrahydronaphthalene-1-carboxylate 
• 66377-63-7 (1,2,3,4-tetrahydronaphthalen-4-yl)methanol 
• 25108-63-8 1-methylene-1,2,3,4-tetrahydronaphthalene 
• 7125-62-4 1,2-benzo-1,3-cycloheptadiene 
• 53155-77-4 N-Cyclohexyl-α-chlor-δ-phenyl-valeraldonitron 

Downstream Products

• 66377-63-7 (1,2,3,4-tetrahydronaphthalen-4-yl)methanol 
• 25634-94-0 (1-methyl-1,2,3,4-tetrahydronaphthalen-1-yl)methanol 

Relevant articles and documents

Deracemization through photochemical E/Z isomerization of enamines

Catalytic deracemization of a-branched aldehydes is a direct strategy to construct enantiopure a-tertiary carbonyls, which are essential to pharmaceutical applications. Here, we report a photochemical E/Z isomerization strategy for the deracemization of a-branched aldehydes by using simple aminocatalysts and readily available photosensitizers. A variety of racemic a-branched aldehydes could be directly transformed into either enantiomer with high selectivity. Rapid photodynamic E/Z isomerization and highly stereospecific iminium/enamine tautomerization are two key factors that underlie the enantioenrichment. This study presents a distinctive photochemical E/Z isomerization strategy for externally tuning enamine catalysis.

Palladium-Catalyzed Allenamide Carbopalladation/Allylation with Active Methine Compounds

A palladium-catalyzed allenamide carbopalladation/allylation with active methine compounds has been developed. Various indoles and isoquinolinones bearing a quaternary carbon center were achieved with good efficiency, a broad substrate scope and good functional group tolerance. This reaction underwent cascade oxidative addition, carbopalladation, and allylic alkylation, and two new C-C bonds were formed in one pot.

Cobalt-Catalyzed Diborylation of 1,1-disubstituted Vinylarenes: A Practical Route to Branched gem-Bis(boryl)alkanes

We report the first catalytic diborylation of 1,1-disubstituted vinylarenes with pinacolborane using a cobalt catalyst generated from bench-stable Co(acac)2 and xantphos. A wide range of 1,1-disubstituted vinylarenes underwent this transformati