182962-33-0Relevant academic research and scientific papers
Iron-catalyzed alkylations of aryl sulfamates and carbamates
Silberstein, Amanda L.,Ramgren, Stephen D.,Garg, Neil K.
, p. 3796 - 3799 (2012)
The alkylation of aryl sulfamates and carbamates using iron catalysis is reported. The method constructs sp2-sp3 carbon-carbon bonds and provides synthetically useful yields across a range of substrates (>35 examples). The directing group ability of sulfamates and carbamates, accompanied by their low reactivity toward conventional cross-couplings, renders these substrates useful for the synthesis of polyfunctionalized arenes.
