18303-04-3Relevant articles and documents
Synthesis, catalytic activity and redox properties of palladium(0) complexes with 15-membered triolefinic macrocyclic ligands containing one, two or three ferrocenyl groups
Llobet, Antoni,Masllorens, Ester,Moreno-Ma?as, Marcial,Pla-Quintana, Anna,Rodríguez, Montserrat,Roglans, Anna
, p. 1425 - 1428 (2002)
A series of 15-membered triolefinic macrocycles containing ferrocenyl groups and their palladium(0) complexes have been synthesized and characterized. Their catalytic activity has been demonstrated in Suzuki-type cross-coupling and in the Heck reaction. Their redox properties have been investigated by means of cyclic voltammetry.
Synthesis method of azetidine silicon precursor compound and method for synthesizing six-membered silicon-nitrogen heterocyclic compound by using azetidine silicon precursor compound
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Paragraph 0091-0095, (2021/06/26)
The invention discloses a synthesis method of an azetidine silicon precursor compound and a method for synthesizing a six-membered silicon nitrogen heterocyclic compound by using the azetidine silicon precursor compound, and belongs to the technical field
DirectN-glycosylation of tosyl and nosyl carbamates with trichloroacetimidate donors
Khanam, Ariza,Mandal, Pintu Kumar
supporting information, p. 15386 - 15391 (2021/09/07)
Under catalyst and additive-free conditions, a convenient and highly efficient eco-friendly method for the stereoselective synthesis ofN-glycofuranosyl and glycofuranosyl sulfonamides has been developed. The two-component reaction of glycofuranosyl trichloroacetimidates with a wide range of tosyl and nosyl carbamate acceptors having varying pKa-values including non-sugar-, and sugar-derived carbamates as well as amino acid-derived carbamates, proceeded smoothly with good yield and β-stereoselectivity. In addition, the selective deprotection ofN-carbamates andN-sulfonyl groups of theN-glycoside functioning as orthogonal protective groups was performed for further functionalization of theN-glycosides.