183119-28-0Relevant articles and documents
Stereocontrolled sequential functionalization in acyclic systems by exploiting internal 1,2-asymmetric induction - Generation of symmetry-related polyamino alcohol motifs
Hanessian, Stephen,Wang, Wengui,Gai, Yonghua
, p. 7477 - 7480 (1996)
Treatment of acyclic γ-ureido α,β-unsaturated esters with lithium dialkyl or diaryl cuprates leads to the corresponding β,γ-substituted esters with high syn-stereoselectivity. The potassium enolates of these compounds react with trisyl azide or the Davis
A solution to the stereochemical problems posed by amaryllidaceae constituents using a highly syn-selective arylcuprate conjugate addition to γ-amino and γ-carbamato-α,β-enoates
Rastogi, Shiva K.,Kornienko, Alexander
, p. 3170 - 3178 (2007/10/03)
Various substituted arylcuprates undergo stereocontrolled additions to l-serine-derived γ-amino- and γ-carbamato-α,β-enoates with high syn-selectivities. The stereochemical outcome of these reactions is fully consistent with the reductive elimination-base