18315-58-7

Basic information

• Product Name: 1,3-Benzenediol, bis(methylcarbamate)
• CAS NO: 18315-58-7
• Molecular Formula: C10H12N2O4
• Molecular Weight: 224.216
• Mol File: 18315-58-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3-Benzenediol, bis(methylcarbamate)(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Benzenediol, bis(methylcarbamate)(18315-58-7)
• EPA Substance Registry System: 1,3-Benzenediol, bis(methylcarbamate)(18315-58-7)

Safety Data

• Hazardous Substances Data: 18315-58-7(Hazardous Substances Data)

Upstream product

• 6642-30-4 methyl N-methylcarbamate 
• 108-46-3 recorcinol 
• 624-83-9 methyl isocyanate 

Relevant articles and documents

Contra-thermodynamic trans-esteripication of carbamates by counter-attack strategy: A viable non-phosgene, non-mic route to carbamate pesticides

Treatment of methyl N-methylcarbaaate (1, R= Me) with phosphorus oxychloride and 1-naphthol results in the formation of the transesterified product, 1-naphthyl N-methylcarbamate (2, Ar=1-naphthy 1) in good yield. Similarly, ethyl N-methylthiocarbamate (5) is converted to 1-naphthyl N-methylcarbamate (2, Ar= 1-naphthyl) on treatment with phosphorus oxychloride and 1-naphthol. The mechanism of these interesting and industrially important transformations is discussed.