18342-49-9Relevant academic research and scientific papers
Sonochemical synthesis of norbornane derivatives using allene cyclopentadiene Diels-Alder cycloaddition
Raj, C. Paul,Dhas, N. Arul,Cherkinski,Gedanken,Braverman
, p. 5413 - 5416 (1998)
The dienophilic reactivity of allenic trichloromethyl sulfoxides under ultrasound irradiation has been investigated. A considerable rate enhancement has been observed for cycloaddition of the and γ-monosubstituted allenyl trichloromethyl sulfoxides to cyc
Phosphorus- and Sulfur-substituted Allenes in Synthesis, III. - β-Keto Sulfoxides from 3-Alkyn-1-ols via Allenic Sulfoxides
Altenbach, Hans-Josef,Soicke, Hartwig
, p. 1096 - 1104 (2007/10/02)
Allenic sulfoxides 3, readily available by sigmatropic rearrangement of sulfenic esters 2 of 3-alkyn-1-ols 1, can be transformed to give β-keto sulfoxides 9 by nucleophilic addition of diethylamine and subsequent hydrolysis of the formed enamines.
