183496-95-9

Basic information

• Product Name: Benzenamine, N-cyclopentyl-4-methoxy-
• CAS NO: 183496-95-9
• Molecular Formula: C12H17NO
• Molecular Weight: 191.273
• Mol File: 183496-95-9.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-cyclopentyl-4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-cyclopentyl-4-methoxy-(183496-95-9)
• EPA Substance Registry System: Benzenamine, N-cyclopentyl-4-methoxy-(183496-95-9)

Safety Data

• Hazardous Substances Data: 183496-95-9(Hazardous Substances Data)

Upstream product

• 96-41-3 Cyclopentanol 
• 104-94-9 4-methoxy-aniline 
• 67705-67-3 N-cyclopentylidene-p-anisidine 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 1003-03-8 Cyclopentamine 
• 63076-51-7 cyclopentane boronic acid 
• 120-92-3 cyclopentanone 
• 696-62-8 para-iodoanisole 
• 779-95-3 Cyclopentyl benzenesulphonate 
• 3558-06-3 cyclopentyl tosylate 

Downstream Products

• 1392010-53-5 C₁₇H₁₈ClN₃O₃ 
• 174181-00-1 3-(1-{[Cyclopentyl-(4-methoxy-phenyl)-carbamoyl]-methyl}-2,4-dioxo-5-phenyl-2,3,4,5-tetrahydro-1H-benzo[b][1,4]diazepin-3-ylmethyl)-indazole-1-carboxylic acid tert-butyl ester 
• 174181-03-4 N-Cyclopentyl-2-(2,4-dioxo-5-phenyl-2,3,4,5,-tetrahydro-benzo[b][1,4]diazepin-1-yl)-N-(4-methoxy-phenyl)-acetamide 
• 174181-02-3 N-Cyclopentyl-N-(4-methoxy-phenyl)-2-(6-phenylamino-cyclohexa-2,4-dienylamino)-acetamide 
• 174181-01-2 2-Bromo-N-cyclopentyl-N-(4-methoxy-phenyl)-acetamide 

Relevant articles and documents

Half-Sandwich Ru(II) Complexes with N,O-Chelate Ligands: Diverse Catalytic Activity for Amine Synthesis in Water

Several types of β-ketoamino based N,O-coordinate half-sandwich ruthenium complexes have been synthesized in moderate to good yields. The stable ruthenium complexes displayed good and diverse catalytic efficiency in reductive amination between aldehydes and amines in aqueous solution. The method gave a facile route for one-pot synthesis of diverse complicated amines with a low catalyst loading by using cheap and less-toxic HCOOH or clean H2 as hydrogen source. Catalyst Ru1 showed the highest catalytic activity of 190 h-1 TOF value in the reductive amination reaction of benzaldehyde with aniline. The corresponding amine products were furnished in excellent yields under the standard catalysis system. The efficient and diverse catalytic activity, broad substance scope, mild conditions, and environmentally benign solvent made this system potentially applicable in industrial production. Ruthenium complexes were characterized using NMR, elemental analysis, and IR techniques to confirm their structure.

Hydrogen-Borrowing Amination of Secondary Alcohols Promoted by a (Cyclopentadienone)iron Complex

Thanks to a highly active catalyst, the scope of the (cyclopentadienone)iron complex-promoted 'hydrogen-borrowing' (HB) amination has been expanded to secondary alcohols, which had previously been reported to react only in the presence of large amounts of co-catalysts. A range of cyclic and acyclic secondary alcohols were reacted with aromatic and aliphatic amines giving fair to excellent yields of the substitution products. The catalyst was also able to promote the cyclization of diols bearing a secondary alcohol group with primary amines to generate saturated N-heterocycles.

Colloid and nanodimensional catalysts in organic synthesis: VIII. Hydrogenation of C=N bond with hydrogen in the presence of colloid nickel

Hydrogenation of azomethines with hydrogen at atmospheric pressure using nickel nanoparticles as catalyst was carried out. Reaction may be used for the preparation of secondary amines under mild conditions on an available catalyst. Continuation of studies will lead to development of a convenient method for the reductive amination of carbonyl compounds.