183598-24-5

Basic information

• Product Name: Silane, (3-cyclohexylidene-3-phenyl-1-propynyl)trimethyl-
• CAS NO: 183598-24-5
• Molecular Formula: C18H24Si
• Molecular Weight: 268.474
• Mol File: 183598-24-5.mol

Chemical Properties

• CAS DataBase Reference: Silane, (3-cyclohexylidene-3-phenyl-1-propynyl)trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (3-cyclohexylidene-3-phenyl-1-propynyl)trimethyl-(183598-24-5)
• EPA Substance Registry System: Silane, (3-cyclohexylidene-3-phenyl-1-propynyl)trimethyl-(183598-24-5)

Safety Data

• Hazardous Substances Data: 183598-24-5(Hazardous Substances Data)

Upstream product

• 1066-54-2 trimethylsilylacetylene 
• 13829-77-1 3-(trimethylsilyl)-1-phenyl-2-propyn-1-one 
• 7333-51-9 cyclohexyl(triphenyl)phosphonium bromide 
• 712-50-5 Cyclohexyl phenyl ketone 

Downstream Products

• 864758-80-5 (1-cyclohexylideneprop-2-ynyl)benzene 

Relevant articles and documents

A new synthesis of trimethylsilyl-substituted enyne and (Z)-enediyne compounds

Trimethylsilyl (TMS)-substituted enynes 9-11, 13-17 and (Z)-enediynes 18 were prepared by dehydration of the TMS-substituted propargyl alcohols 1-8 with polyphosphoric acid trimethylsilyl ester.

Ruthenium-catalyzed cycloisomerization of cis-3-en-1-ynes to cyclopentadiene and related derivatives through a 1,5-sigmatropic hydrogen shift of ruthenium vinylidene intermediates

We report a new ruthenium-catalyzed cycloisomerization of unactivated cis-3-en-1-ynes, which produces substituted cyclopentadiene and related derivatives. The mechanism of this cyclization is proposed to involve a [1,5]-sigmatropic hydrogen shift of ruthenium-vinylidene intermediates on the basis of deuterium-labeling experiments. Copyright