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(CYCLOHEXYLMETHYL)TRICHLOROSILANE, with the chemical formula C7H15Cl3Si, is a colorless liquid characterized by a pungent odor. It is a versatile reagent for the introduction of cyclohexylmethyl groups onto various substrates, playing a significant role in the synthesis of functionalized siloxanes and silicone polymers. (CYCLOHEXYLMETHYL)TRICHLOROSILANE is also instrumental in the production of coatings, adhesives, and sealants, making it a valuable asset in the chemical industry.

18388-16-4

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18388-16-4 Usage

Uses

Used in Chemical Synthesis:
(CYCLOHEXYLMETHYL)TRICHLOROSILANE is used as a reagent for the introduction of cyclohexylmethyl groups onto various substrates, facilitating the creation of a wide range of chemical compounds.
Used in the Production of Silicone Polymers:
In the polymer industry, (CYCLOHEXYLMETHYL)TRICHLOROSILANE serves as a precursor in the synthesis of functionalized siloxanes and silicone polymers, contributing to the development of materials with diverse applications.
Used in the Manufacturing of Coatings, Adhesives, and Sealants:
(CYCLOHEXYLMETHYL)TRICHLOROSILANE is utilized in the production of coatings, adhesives, and sealants, enhancing the performance and properties of these products.
Safety Precautions:
Due to its reactivity, (CYCLOHEXYLMETHYL)TRICHLOROSILANE should be handled and stored with caution. It is corrosive and can cause irritation to the skin, eyes, and respiratory tract upon exposure, necessitating proper safety measures during its use.

Check Digit Verification of cas no

The CAS Registry Mumber 18388-16-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,8,3,8 and 8 respectively; the second part has 2 digits, 1 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 18388-16:
(7*1)+(6*8)+(5*3)+(4*8)+(3*8)+(2*1)+(1*6)=134
134 % 10 = 4
So 18388-16-4 is a valid CAS Registry Number.
InChI:InChI=1/C14H21N/c1-2-5-13(6-3-1)7-4-8-14-9-11-15-12-10-14/h1-3,5-6,14-15H,4,7-12H2

18388-16-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name trichloro(cyclohexylmethyl)silane

1.2 Other means of identification

Product number -
Other names Cyclohexylmethyl-trichlorosilan

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:18388-16-4 SDS

18388-16-4Relevant academic research and scientific papers

Contra-thermodynamic Olefin Isomerization by Chain-Walking Hydrofunctionalization and Formal Retro-hydrofunctionalization

Hanna, Steven,Butcher, Trevor W.,Hartwig, John F.

supporting information, p. 7129 - 7133 (2019/09/12)

We report a contra-thermodynamic isomerization of internal olefins to terminal olefins driven by redox reactions and formation of Si-F bonds. This process involves chain-walking hydrosilylation of internal olefins and subsequent formal retro-hydrosilylation. The process rests upon the high activities of platinum hydrosilylation catalysts for isomerization of metal alkyl intermediates and a new, metal-free process for the conversion of alkylsilanes to alkenes. By this approach, 1,2-disubstituted and trisubstituted olefins are converted to terminal olefins.

Hydrosilylation of cyclohexene, 1-methylcyclohexene, and isopropylidenecyclohexane

Yarosh,Zhilitskaya,Yarosh,Albanov,Voronkov

, p. 1895 - 1899 (2007/10/03)

Hydrosilylation of cyclohexene and isopropylidenecyclohexane with chloro(methyl)silanes Me3-n SiHCln (n = 1-3) gives rise to cyclohexyl- and chloro(2-cyclohexylpropyl)methylsilanes. Hydrosilylation of 1-methylcyclohexene with chlorodimethylsilane (n = 1) occurs anomalously and involves double-bond migration to form a mixture of seven compounds: the cis and trans isomers of 2-, 3-, 4-chlorodimethyl(methylcyclohexyl)silanes and chlorodimethyl(cyclohexylmethyl)silane. Chlorodimethylsilane (n = 2) adds to 1-methylcyclohexene to form a mixture of the cis and trans isomers of dichloro(methyl)(2-methylcyclohexyl)silane and dichloro(cyclohexylmethyl) methylsilane. With trichlorosilane (n = 3), no other products than trichloro(cyclohexylmethyl)silane are formed. The hydrosilylation products were reacted with ethynylmagnesium bromide to synthesize the corresponding ethynyl derivatives. 2004 MAIK "Nauka/Interperiodica".

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