183903-04-0

Basic information

• Product Name: (+)-γ-cyclohomocitral
• Synonyms: (+)-γ-cyclohomocitral
• CAS NO: 183903-04-0
• Molecular Weight: 166.263
• Mol File: 183903-04-0.mol

Chemical Properties

• CAS DataBase Reference: (+)-γ-cyclohomocitral(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-γ-cyclohomocitral(183903-04-0)
• EPA Substance Registry System: (+)-γ-cyclohomocitral(183903-04-0)

Safety Data

• Hazardous Substances Data: 183903-04-0(Hazardous Substances Data)

Upstream product

• 112243-60-4 (1'S)-2-(2',2'-dimethyl-6'-methylene-cyclohexyl)-ethanol 
• 183903-01-7 (1'R,3'R)-2-(3'-hydroxy-2',2'-dimethyl-6'-methylene-cyclohexyl)-ethyl trimethylacetate 
• 357924-22-2 8,8-dimethyl-2-methylene-6-oxabicyclo[3.2.1]octan-7-ol 
• 609797-72-0 (S)-2-(2-methoxyvinyl)-1,1-dimethyl-3-methylidenecyclohexane 
• 609797-71-9 (1S,3R)-3-(2-methoxyvinyl)-2,2-dimethyl-4-methylidenecyclohexanol 
• 358339-06-7 (1R,5S)-(+)-8,8-dimethyl-2-methylene-6-oxabicyclo[3.2.1]octan-7-one 

Downstream Products

• 609797-73-1 2-((S)-2,2-Dimethyl-6-methylene-cyclohexyl)-1-furan-3-yl-ethanol 
• 609797-74-2 (E)-4-((S)-2,2-Dimethyl-6-methylene-cyclohexyl)-2-methyl-but-2-enal 

Relevant articles and documents

First total synthesis and assignment of the stereochemistry of crispatenine

(Figure Presented) The first racemic and enantioselective synthesis of crispatenine 1 has been achieved, which involved a few steps, enabling the assignment of the absolute and relative configurations.

First enantioselective synthesis and determination of the absolute configuration of natural (+)-dehydro-β-monocyclonerolidol

The enantioselective synthesis and determination of the absolute configuration of (+)-dehydro-β-monocyclonerolidol, a natural product isolated from the liverwort P. subobtusa, has been achieved starting from (+)-karahana lactone as an enantiopure building

Enantioselective synthesis of γ-cyclohomocitral, pallescensone, and ancistrodial

A simple and efficient enantioselective synthesis of γ-cyclohomocitral, a key and versatile intermediate for the synthesis of some monocyclofarnesane terpenoids, is described. This features a highly sitoselective Sharpless asymmetric dihydroxylation of a