183903-04-0Relevant articles and documents
First total synthesis and assignment of the stereochemistry of crispatenine
Bourdron, Julien,Commeiras, Laurent,Audran, Gerard,Vanthuyne, Nicolas,Hubaud,Parrain, Jean-Luc
, p. 3770 - 3775 (2008/02/04)
(Figure Presented) The first racemic and enantioselective synthesis of crispatenine 1 has been achieved, which involved a few steps, enabling the assignment of the absolute and relative configurations.
First enantioselective synthesis and determination of the absolute configuration of natural (+)-dehydro-β-monocyclonerolidol
Palombo, Elie,Audran, G.érard,Monti, Honoré
, p. 6463 - 6464 (2007/10/03)
The enantioselective synthesis and determination of the absolute configuration of (+)-dehydro-β-monocyclonerolidol, a natural product isolated from the liverwort P. subobtusa, has been achieved starting from (+)-karahana lactone as an enantiopure building
Enantioselective synthesis of γ-cyclohomocitral, pallescensone, and ancistrodial
Vidari, Giovanni,Lanfranchi, Gianluigi,Masciaga, Francesca,Moriggi, Jean-Dominique
, p. 3009 - 3020 (2007/10/03)
A simple and efficient enantioselective synthesis of γ-cyclohomocitral, a key and versatile intermediate for the synthesis of some monocyclofarnesane terpenoids, is described. This features a highly sitoselective Sharpless asymmetric dihydroxylation of a