18402-58-9

Basic information

• Product Name: (E)-1-(diethylmethyl-silyloxy)-3-phenyl-1-propene
• CAS NO: 18402-58-9
• Molecular Weight: 234.414
• Mol File: 18402-58-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-1-(diethylmethyl-silyloxy)-3-phenyl-1-propene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(diethylmethyl-silyloxy)-3-phenyl-1-propene(18402-58-9)
• EPA Substance Registry System: (E)-1-(diethylmethyl-silyloxy)-3-phenyl-1-propene(18402-58-9)

Safety Data

• Hazardous Substances Data: 18402-58-9(Hazardous Substances Data)

Upstream product

• 14371-10-9 (E)-3-phenylpropenal 
• 760-32-7 diethylmethylsilane 

Relevant articles and documents

Silylations of α,β-unsaturated and aromatic carbonyl compounds with cobalt carbonyls

[η3-η5-(Silyloxy-alkenyl)]-cobalt carbonyls and various silyl ethers were formed in the cobalt carbonyl mediated silylations of α,β-unsaturated and aromatic carbonyl compounds. A silyloxonium tetracarbonylcobaltate tight ion pair was suggested as a common intermediate, which provides the products through a radical pair in the cases of aromatic aldehydes and ketones.