184044-84-6Relevant academic research and scientific papers
New monodentate chiral phosphine 2,6-dimethyl-9-phenyl-9-phosphabicyclo[3.3.1]nonane(9-PBN): Application to asymmetric allylic substitution reaction
Hamada, Yasumasa,Seto, Noriko,Ohmori, Hiroki,Hatano, Keiichiro
, p. 7565 - 7568 (1996)
New monodentate chiral phosphines, (+)- and (-)-2,6-dimethyl-9-phenyl-9-phosphabicyclo[3.3.1]nonanes ((+)- and (-)-9-PBNs), were prepared from 1,5-dimethyl-1,5-cyclooctadiene, and their application to the asymmetric allylic substitution reaction proved th
Synthesis of new chiral amines, 2,6-dimethyl- 9-azabicyclo[3.3.1]nonane and its derivatives
Hamada, Yasumasa,Okamoto, Naoki,Hara, Osamu
, p. 929 - 934 (2000)
New chiral amines, 2,6-dimethyl-9-azabicyclo[3.3.1]nonane and its derivatives, were prepared starting from commercially available 1,5-dimethyl- 1,5-cyclooctadiene followed by substitution reaction of the intermediate ditosylate with p-toluenesulfonamide u
Synthesis of 2,6-dimethyl-9-aryl-9-phosphabicyclo[3.3.1]nonanes: their application to asymmetric synthesis of chiral tetrahydroquinolines and relatives
Hara, Osamu,Koshizawa, Tomoaki,Makino, Kazuishi,Kunimune, Iyo,Namiki, Atsushi,Hamada, Yasumasa
, p. 6170 - 6181 (2008/02/05)
Synthesis of 2,6-dimethyl-9-aryl-9-phosphabicyclo[3.3.1]nonanes from 1,5-cyclooctadiene and their application to asymmetric cyclization leading to chiral tetrahydroquinolines and relatives through palladium-catalyzed allylic alkylation are described.
