18419-09-5

Basic information

• Product Name: 3,7-Dimethyl-6-octenyl(trimethylsilyl) ether
• Synonyms: 3,7-Dimethyl-1-[(trimethylsilyl)oxy]-6-octene;3,7-Dimethyl-6-octenyl(trimethylsilyl) ether
• CAS NO: 18419-09-5
• Molecular Formula: C₁₃H₂₈OSi
• Molecular Weight: 228.45
• Mol File: 18419-09-5.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 90-91 °C(Press: 4.5 Torr)
• Appearance: /
• Density: 0.8395 g/cm3(Temp: 30 °C)
• CAS DataBase Reference: 3,7-Dimethyl-6-octenyl(trimethylsilyl) ether(CAS DataBase Reference)
• NIST Chemistry Reference: 3,7-Dimethyl-6-octenyl(trimethylsilyl) ether(18419-09-5)
• EPA Substance Registry System: 3,7-Dimethyl-6-octenyl(trimethylsilyl) ether(18419-09-5)

Safety Data

• Hazardous Substances Data: 18419-09-5(Hazardous Substances Data)

Upstream product

• 106-22-9 Citronellol 
• 107-46-0 Hexamethyldisiloxane 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 18243-21-5 trimethylsilyl formate 
• 1349833-44-8 lithium (2S,3S,4S,5R,6S)-6-(4-((4-((3,7-dimethyloct-6-enyloxy)(phenethoxy)methyl)phenylcarbamoyloxy)-methyl)phenoxy)-3,4,5-trihydroxytetrahydro-2H-pyran-2-carboxylate 
• 1349833-43-7 methyl (2S,3S,4S,5R,6S)-3,4,5-triacetoxy-6-(4-((4-((3,7-dimethyloct-6-enyloxy)(phenethoxy)methyl)phenylcarbamoyloxy)-methyl)phenoxy)tetrahydro-2H-pyran-2-carboxylate 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 1349833-34-6 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzyl 4-(bis(3,8-dimethylnon-7-enyloxy)methyl)phenylcarbamate 
• 1349833-43-7 methyl (2S,3S,4S,5R,6S)-3,4,5-triacetoxy-6-(4-((4-((3,7-dimethyloct-6-enyloxy)(phenethoxy)methyl)phenylcarbamoyloxy)-methyl)phenoxy)tetrahydro-2H-pyran-2-carboxylate 
• 106-22-9 Citronellol 

Relevant articles and documents

Silylation of O-H bonds by catalytic dehydrogenative and decarboxylative coupling of alcohols with silyl formates

The silylation of O-H bonds is a useful methodology in organic synthesis and materials science. While this transformation is commonly achieved by reacting alcohols with reactive chlorosilanes or hydrosilanes, we show herein for the first time that silylformates HCO2SiR3 are efficient silylating agents for alcohols, in the presence of a ruthenium molecular catalyst.

Efficient and convenient procedure for protection of hydroxyl groups to the THP, THF and TMS ethers and oxidation of these ethers to their aldehydes or ketones in [BPy]FeCl4 as a low cost room temperature ionic liquid

Alcohols were converted to the corresponding THP, THF or TMS ethers in high to excellent yields in 1-n-butylpyridinium chloroferrate media as a stable and low cost room temperature ionic liquid. In addition, oxidation of these ethers to their aldehydes or ketones without any overoxidation reactions in this ionic liquid was also performed.