18448-45-8Relevant articles and documents
Metal-free TEMPO-catalyzed oxidative C-C bond formation from Csp 3-H bonds using molecular oxygen as the oxidant
Zhang, Bo,Cui, Yuxin,Jiao, Ning
supporting information; scheme or table, p. 4498 - 4500 (2012/06/01)
An efficient TEMPO-catalyzed oxidative C-C bond formation with two Csp 3-H bonds using molecular oxygen as the oxidant has been developed. The novel transformation provides a new strategy for the TEMPO-O2 catalysis to construct C-C bonds. The advantages of this method include: (1) relatively mild and neutral conditions; (2) simplicity and safety of operation; (3) a stoichiometric amount of dangerous oxidants, any transition metals, additives, even solvent, is not required.