184579-08-6

Basic information

• Product Name: (Methyl-hydrazono)-phenyl-acetic acid ethyl ester
• CAS NO: 184579-08-6
• Molecular Weight: 206.244
• Mol File: 184579-08-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Methyl-hydrazono)-phenyl-acetic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (Methyl-hydrazono)-phenyl-acetic acid ethyl ester(184579-08-6)
• EPA Substance Registry System: (Methyl-hydrazono)-phenyl-acetic acid ethyl ester(184579-08-6)

Safety Data

• Hazardous Substances Data: 184579-08-6(Hazardous Substances Data)

Upstream product

• 153864-57-4 ethyl α-(E-phenylhydrazono)benzeneacetate 
• 1603-79-8 phenylglyoxylic acid ethyl ester 
• 60-34-4 methylhydrazine 

Relevant articles and documents

Oxidation of hydrazones by hypervalent organoiodine reagents: Regeneration of the carbonyl group and facile syntheses of α-acetoxy and α-alkoxy azo compounds

Various hydrazone derivatives of α-keto esters were prepared. The carbonyl group was readily regenerated in high yield from phenylhydrazones through oxidative hydrolysis using hypervalent organoiodine(III) reagents either bis(trifluoroacetoxy)-iodobenzene (BTIB) in aqueous acetonitrile or hydroxy(tosyloxy)iodobenzene (HTIB) in chloroform. α-Acotxy phenyl- or methylazo compounds were readily synthesized by oxidation of the corresponding hydrazones with iodobenzene diacetate (IBDA) in dichloromethane or acetic acid. α-Methoxy phenyl- or methylazo compounds were also prepared by oxidation of the hydrazones in methanol. The mechanisms of the oxidation reactions are discussed.