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Bicyclo[3.1.0]hexan-2-one, 6,6-dimethyl-, also known as 6,6-dimethylbicyclo[3.1.0]hexan-2-one, is an organic compound with the molecular formula C8H12O. It is a cyclic ketone characterized by a six-membered ring with two methyl groups attached to the carbon atoms at positions 6 and 6. Bicyclo[3.1.0]hexan-2-one, 6,6-dimethyl- is known for its unique structure and is often used in the synthesis of various organic compounds, particularly in the pharmaceutical and chemical industries. It is a colorless liquid with a pungent odor and is insoluble in water but soluble in organic solvents. The compound is also known for its potential applications in the development of new drugs and other chemical products due to its interesting chemical properties.

1846-48-6

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1846-48-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1846-48-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,8,4 and 6 respectively; the second part has 2 digits, 4 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 1846-48:
(6*1)+(5*8)+(4*4)+(3*6)+(2*4)+(1*8)=96
96 % 10 = 6
So 1846-48-6 is a valid CAS Registry Number.

1846-48-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name 6,6-dimethylbicyclo[3.1.0]hexan-2-one

1.2 Other means of identification

Product number -
Other names 6,6-Dimethyl-bicyclo<3.1.0>-2-hexanon

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1846-48-6 SDS

1846-48-6Upstream product

1846-48-6Downstream Products

1846-48-6Relevant academic research and scientific papers

91. Photorearrangement of 4,4-Dimethylcyclohex-2-enones with Alkyl or Fluoro Substituents at C(5) and C(6): in Search of the Mechanism

Cruciani, Giuliano,Margaretha, Paul

, p. 890 - 895 (1990)

The photorearrangement of cyclohex-2-enones 4a-h to bicyclohexan-2-ones 5 and cyclopent-2-enones 6 (λ = 350 nm, MeCN) was investigated.Both the quantum yield (Φ-4 = 0.004 - 0.024) and the product ratio (5/6 = 65:35 - 31:69) vary only over a rather small range, indicating the rearrangement to be relatively insensitive to substituents on C(5) or C(6).Compounds 4b, 4c, and 4g with just one alkyl group at either C(6) or C(5) rearrange selectively to the diastereoisomer 5 with alkyl group and three-membered ring in trans-configuration, while 6-fluorocyclohex-2-enones 4d and 4f afford mixtures of diastereoisomeric bicyclohexanones.Mechanistic conclusions regarding an intermediate trimethylene biradical are presented.

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