18461-45-5Relevant academic research and scientific papers
Phosphorus-Carbon Bond Forming Reactions of Diphenylphosphenium and Diphenylphosphine Triflate Complexes of Tungsten
Jayaraman, Arumugam,Sterenberg, Brian T.
, p. 2367 - 2377 (2016/08/02)
The complex [W(CO)5{PClPh2}] reacts with AlCl3 to form a mixture of the phosphenium complex [W(CO)5{PPh2}][AlCl4] and an isocarbonyl, with GaCl3 to form [W(CO)5{PPh2}][GaCl4], and with silver trifluoromethanesulfonate to form [W(CO)5{P(OSO2CF3)Ph2}]. All three complexes react as strong P electrophiles, undergoing electrophilic substitution reactions with aromatic and heteroaromatic compounds, alkenes, and alkynes, to form aromatic and heteroaromatic phosphines, allyl phosphines, and alkynyl phosphines, respectively. Alkenes lacking cleavable γ-H atoms and internal alkynes undergo tandem electrophilic addition/substitution reactions, adding between the P and one of the phenyl rings to form fused P heterocycles. The newly formed phosphines can be removed from the tungsten complex by photolysis in the presence of bis(diphenylphosphino)ethane.
Sequential electrophilic P-C bond formation in metal-coordinated chlorophosphines
Jayaraman, Arumugam,Jacob, Tyler V.,Bisskey, Jeff,Sterenberg, Brian T.
supporting information, p. 8788 - 8791 (2015/05/20)
In the presence of chloride abstractors, metal-coordinated chlorophosphines undergo facile room-temperature electrophilic substitution reactions with unsaturated organic substrates, leading to P-C bond formation. This methodology can be applied sequential
