18465-83-3

Basic information

• Product Name: methyl 4,6-dideoxy-β-D,L-arabino-hexopyranoside
• CAS NO: 18465-83-3
• Molecular Weight: 162.186
• Mol File: 18465-83-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl 4,6-dideoxy-β-D,L-arabino-hexopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4,6-dideoxy-β-D,L-arabino-hexopyranoside(18465-83-3)
• EPA Substance Registry System: methyl 4,6-dideoxy-β-D,L-arabino-hexopyranoside(18465-83-3)

Safety Data

• Hazardous Substances Data: 18465-83-3(Hazardous Substances Data)

Upstream product

• 28251-53-8 methyl 2,3,4-tri-O-acetyl-α-L-rhamnopyranoside 
• 863444-71-7 Acetic acid (2R,3R,4R,6S)-2-methoxy-6-methyl-4-trifluoromethanesulfonyloxy-tetrahydro-pyran-3-yl ester 
• 863444-69-3 methyl-2-O-acetyl-4,6-dideoxy-α-L-lyxo-hexapyranoside 
• 863444-74-0 methyl-2,3-di-O-acetyl-4,6-dideoxy-α-L-arabino-hexopyranoside 

Downstream Products

• 172291-75-7 methyl O-(2,3-di-O-benzoyl-4,6-dideoxy-α-L-lyxo-hexopyranosyl)-(1<*>2)-3,4,6-tri-O-benzoyl-α-D-galactopyranoside 
• 172291-71-3 2,3-di-O-benzoyl-4,6-dideoxy-α-L-lyxo-hexopyranosyl chloride 
• 172291-69-9 methyl 2,3-di-O-benzoyl-4,6-dideoxy-α-L-lyxo-hexopyranoside 

Relevant articles and documents

Enzymatic approach to enantiomerically pure 5-alken-2,4-diols and 4-hydroxy-5-alken-2-ones: Application to the synthesis of chiral synthons

Enantiomerically pure 1,3-diols 1-3 were obtained by a chemoenzymatic approach (lipase PS from Burkholderia cepacia). These diols were converted into useful chiral synthons, which could be considered homologues of glyceraldehyde and glyceric acid acetonid

SYNTHESIS OF METHYL 2,6- AND 3,6-DIDEOXY-α-L-ARABINO-HEXOPYRANOSIDES AND METHYL 4,6-DIDEOXY-α-L-LYXO-HEXOPYRANOSIDES

A convenient method of synthesizing methyl 2,6- and 3,6-dideoxy-α-L-arabino-hexopyranosides and of methyl 4,6-dideoxy-α-L-lyxo-hexopyranoside is proposed.