184763-00-6Relevant academic research and scientific papers
Total synthesis of the proposed structure of astakolactin
Tonoi, Takayuki,Mameda, Keisuke,Fujishiro, Moe,Yoshinaga, Yutaka,Shiina, Isamu
, p. 2421 - 2427 (2014/12/12)
The first total synthesis of the proposed structure of astakolactin, a sesterterpene metabolite isolated from the marine sponge Cacospongia scalaris, has been achieved, mainly featuring Johnson-Claisen rearrangement, asymmetric Mukaiyama aldol reaction an
First asymmetric synthesis of the marine furanosesterterpene natural product, (18S)-variabilin, employing enzymatic desymmetrization of propanediol derivatives
Takabe, Kunihiko,Hashimoto, Hiroya,Sugimoto, Hideki,Nomoto, Masaru,Yoda, Hidemi
, p. 909 - 912 (2007/10/03)
An efficient and stereodefined process is described for the first preparation of the marine furanosesterterpene tetronic acid, (18S)-variabilin, featuring lipase-catalyzed asymmetric desymmetrization of two types of propanediol precursors incorporating the terpene skeleton.
