184916-47-0Relevant academic research and scientific papers
Hydrolysis of (η5-C5Me5)MMe4 (M = Mo, W) and the formation of organometallic oxides with μ3-CH methylidyne and μ-CH2 methylidene groups: Model compounds for catalysis on metal oxide surfaces
Guzyr, Olexandr I.,Prust, J?rg,Roesky, Herbert W.,Lehmann, Christopher,Teichert, Markus,Cimpoesu, Fanica
, p. 1549 - 1555 (2008/10/08)
The hydrolysis of (η5-C5Me5)WMe4 leads to the formation of the two compounds (η5-C5-Me5)2W2O 2(μ-CH2)2 (6) and (η5-C5Me5)2W2O 2(μ-CH2)(μ-O) (9), containing both methylidene and oxo moieties in one molecule. Reaction of (η5-C5Me5)MoMe4 with water leads to the trinuclear cluster (η5-C5Me5)3Mo 3(μ-O)2(μ-CH2)(μ3-CH) (10) with oxo, methylidene, and methylidyne groups. Compounds 6, 9, and 10 were characterized by single-crystal X-ray structural analysis. 6, 9, and 10 can be considered as model compounds for catalysis on metal oxide surfaces.
An efficient synthetic route to primary and secondary condensation products of silanetriols starting from (arylamino)trichlorosilanes
Murugavel, Ramaswamy,Boettcher, Peter,Voigt, Andreas,Walawalkar, Mrinalini G.,Roesky, Herbert W.,Parisini, Emilio,Teichert, Markus,Noltemeyer, Mathias
, p. 2417 - 2418 (2007/10/03)
Stoichiometry dependent hydrolysis of (arylamino)-silyltrichlorides using anhydrous N2H4 as the HCl acceptor and dehydrating agent leads to the formation of the primary and secondary condensation products of silanetriols, tetrahydrox
