184955-56-4

Upstream product

• 184955-52-0 6-[(S)-4-(tert-Butyl-dimethyl-silanyloxy)-2-oxo-heptyl]-2,3,4-trimethoxy-N,N-dimethyl-benzamide 
• 184955-48-4 (4R,5S)-3-((S)-3-Hydroxy-hexanoyl)-4-methyl-5-phenyl-oxazolidin-2-one 
• 184955-50-8 (S)-3-(tert-Butyl-dimethyl-silanyloxy)-hexanoic acid methoxy-methyl-amide 
• 184955-54-2 6-((S)-4-Hydroxy-2-oxo-heptyl)-2,3,4-trimethoxy-N,N-dimethyl-benzamide 

Relevant academic research and scientific papers

Enantioselective synthesis of fusarentin methyl ethers: Insecticidal metabolites of Fusarium larvarum

Fusarentin 4,5-dimethyl ether (1) and its 4-desmethoxy analogue are synthesised via acylation of the benzylic anion of N,N-dimethyl-2,3,4-trimethoxy-6-methylbenzamide (9) and N,N-dimethyl-2,4-dimethoxy-6-methylbenzamide (8) with N-methoxy-N-methyl-(S)-3-tert-butyldimethylsilyloxyhexanamide (13): Subsequent reduction of ketone (15) to the anti-1,3-diol (16) and acid catalysed cyclisation gives (1).