18500-63-5 Usage
Description
A sesquiterpenoid alkaloid found as a metabolite of Clitocybe illudens. On
decarboxylation, the methoxyl group is simultaneously cleaved to yield 7: 7-
dimethyl-9-hydroxy-6: 7 -dihydro-8H-cyclopenta [g l-isoq uinoline.
References
Nair et al., J. Org. Chem., 34, 240 (1969)
Check Digit Verification of cas no
The CAS Registry Mumber 18500-63-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,8,5,0 and 0 respectively; the second part has 2 digits, 6 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 18500-63:
(7*1)+(6*8)+(5*5)+(4*0)+(3*0)+(2*6)+(1*3)=95
95 % 10 = 5
So 18500-63-5 is a valid CAS Registry Number.
InChI:InChI=1/C16H17NO3/c1-16(2)6-10-11(7-16)14(20-3)12-8-17-5-4-9(12)13(10)15(18)19/h4-5,8H,6-7H2,1-3H3,(H,18,19)
18500-63-5Relevant articles and documents
Microwave-mediated nickel-catalyzed cyclotrimerization reactions: Total synthesis of illudinine
Teske, Jesse A.,Deiters, Alexander
, p. 342 - 345 (2008)
(Chemical Equation Presented) Rapid and efficient [2 + 2 + 2] cyclotrimerization reactions were discovered through the application of microwave irradiation in conjunction with a Ni(CO)2(PPh 3)2 catalyst. This enables the f
Synthesis of Illudinine from Dimedone
Morrison, Alec E.,Hoang, Tung T.,Birepinte, Mélodie,Dudley, Gregory B.
, p. 858 - 861 (2017/02/26)
A total synthesis of the illudalane sesquiterpene illudinine was realized in eight steps and 14% overall yield from commercially available dimedone. The approach features tandem fragmentation/Knoevenagel-type condensation and microwave-assisted oxidative
