185034-25-7Relevant academic research and scientific papers
Changing the ortho/para ratio in aromatic acylation reactions by changing reaction conditions: A mechanistic explanation from kinetic measurements
Effenberger,Maier
, p. 3429 - 3433 (2001)
Kinetic measurements of the acylation of toluene (2a) and p-xylene (2b), side-chain deuterated toluene (2a-d3), as well as perdeuterated toluene (2a-d8) and p-xylene (2b-d10) with the aroyl triflate 1 in 1,2-dichloroethane
The first unequivocal evidence of the reacting electrophile in aromatic acylation reactions
Effenberger, Franz,Eberhard, Joachim K.,Maier, Andreas H.
, p. 12572 - 12579 (2007/10/03)
The acylation of aromatic compounds with aroyl triflates can be performed in organic solvents (1,2-dichloroethane) without Friedel-Crafts catalysts. These reaction conditions allow kinetic investigations of the reaction in homogeneous solution. From rate
