185047-16-9Relevant academic research and scientific papers
Synthesis of functionalized cyclopentanes, cyclohexanes and cycloheptanes by a silicon-induced domino reaction
Michel, Tycho,Kirschning, Andreas,Beier, Christian,Braeuer, Nico,Schaumann, Ernst,Adiwidjaja, Gunadi
, p. 1811 - 1821 (2007/10/03)
1,3-Functionalized cyclopentanes, -hexanes and -heptanes are obtained by addition of lithiated silyldithioacetals 7 to epoxyhomoallyl tosylates 4-6. The reaction involves a cascade of epoxide ring opening, of Brook 1,4-rearrangement and tosylate substitut
