185065-99-0Relevant academic research and scientific papers
Synthesis and stereochemistry of bis(cyclopalladium) complexes of 1,1′-bis [1-(arylimino)ethyl]ferrocenes
Wu, Yang Jie,Liu, Yuan Hong,Yang, Li,Zhu, Qixiu
, p. 335 - 339 (2008/10/09)
Double cyclopalladation of 1,1′-bis[(arylimino)ethyl]ferrocenes with Li2PdCl4 followed by treatment with PPh3 afforded meso and dl stereoisomers of bis(palladium) complexes and the individual stereoisomers were isolated successfully by column chromatography. The composition and the structure of the metallocycles were characterized by elemental analysis, IR and 1H NMR spectroscopy. A mechanism for the formation of stereoisomers in the cyclopalladation reaction was suggested. Copyright
