185129-90-2

Basic information

• Product Name: 2-(4-chlorophenyl)iMidazole[4,5f][1,10]phenanthroline
• Synonyms: 2-(4-chlorophenyl)iMidazole[4,5f][1,10]phenanthroline
• CAS NO: 185129-90-2
• Molecular Formula: C₁₉H₁₁ClN₄
• Molecular Weight: 330.77
• Mol File: 185129-90-2.mol
• Article Data: 12

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-(4-chlorophenyl)iMidazole[4,5f][1,10]phenanthroline(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-chlorophenyl)iMidazole[4,5f][1,10]phenanthroline(185129-90-2)
• EPA Substance Registry System: 2-(4-chlorophenyl)iMidazole[4,5f][1,10]phenanthroline(185129-90-2)

Safety Data

• Hazardous Substances Data: 185129-90-2(Hazardous Substances Data)

Upstream product

• 873-76-7 para-Chlorobenzyl alcohol 
• 106-43-4 para-chlorotoluene 
• 104-88-1 4-chlorobenzaldehyde 
• 79790-36-6 9,10-diamino-1,4,5,8-tetraazaphenanthrene 
• 1073-67-2 4-vinylbenzyl chloride 
• 66-71-7 1,10-Phenanthroline 
• 27318-90-7 1,10-phenanthroline-5,6-dione 

Relevant articles and documents

Liposomes encapsulated iridium(III) polypyridyl complexes enhance anticancer activity in vitro and in vivo

Three iridium(III) complexes [Ir(ppy)2(CPIP)](PF6) (Ir-1, ppy = 2-phenylpyridine, CPIP = 2-(4-chlorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline), [Ir(ppy)2(DCPIP)](PF6) (Ir-2, DCPIP = 2-(3,4-dichlorophenyl)-1H

An optical material for the detection of trace S2O3 2? in milk based on a copper complex

A novel S2O3 2? luminescent sensor (Cu2+-p-CPIP) was developed and the presence of S2O3 2? caused an obvious fluorescence enhancement at 420?nm upon excitation at 330?nm, which c

A Remote ‘Imidazole’-Based Ruthenium(II) Para-Cymene Pre-catalyst for the Selective Oxidation Reaction of Alkyl Arenes and Alcohols

Herein we disclosed the use of a remote ‘imidazole’-based precatalyst [(para-cymene)RuII(L)Cl]+, C-1 where L=2-(4-substituted-phenyl)-1H-imidazo[4,5-f][1,10] phenanthroline) for the selective oxidation of a variety of alkyl arenes/heteroarenes and alcohols to their corresponding aldehydes or ketones in presence of tert-butyl hydroperoxide (TBHP). The remote ‘imidazole’ moiety present in the complex facilitates the activation of oxidant and subsequent generation of active species via the release of para-cymene from C-1, which in-turn was less effective without the ‘imidazole’ moiety. The mechanistic features of C-1 promoted oxidation of alkyl arenes were also assessed from spectroscopic, kinetic, and few control experiments. The substrate scope for C-1 promoted oxidation reaction was assessed based on the selective oxidation of 27-different alkyl arenes/heteroarenes and 25 different alcohols to their corresponding aldehydes/ketones in moderate to good yields.

Remote ‘Imidazole’ Based Ruthenium(II) p-Cymene Precatalyst for Selective Oxidative Cleavage of C?C Multiple Bonds

The dual role of remote ‘imidazole’ attached with the precatalyst [(p-cymene)RuII(L)Y]+ (L=2-(4-substituted-phenyl)-1H-imidazo[4,5-f][1,10] phenanthroline, Y=chloride/solvent) was explored for the selective oxidative cleavage of C?C multiple bonds to acetals/aldehydes. The presence of ‘imidazole’ in the precatalysts was found to be useful for the activation of oxidant and release of p-cymene from the precatalysts, which in turn was not effective without the ‘imidazole’ moiety. The mechanistic aspects of the precatalyst were evaluated from spectroscopic, kinetic, and few other controlled experiments. The loss of p-cymene is the key step for the reaction and found to be faster in solvated precatalyst, [(p-cymene)RuII(L)(MeOH)]++ and thus showed 3–4-fold more effective as compared to [(p-cymene)RuII(L)Cl]+.